• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    flexible tube body and method of producing the same. The present invention relates to a flexible tube body and method of producing a flexible tube body. the method includes providing a tubular layer; and directing a chemical reagent toward the surface portion of the tubular layer, wherein the tubular layer comprises an extruded polymer, and wherein the chemical reagent is suitable for changing one or more physical or mechanical properties in proportion to the thickness of the extruded tubular layer .
    公开号:BR102013009665B1
    申请号:R102013009665-2
    申请日:2013-04-19
    公开日:2021-06-01
    发明作者:Iwan Rhys Harries；Neville Dodds
    申请人:Ge Oil & Gas Uk Limited；
    IPC主号:
    专利说明:

    [001] The present invention relates to a flexible tube body and method of producing the same. In particular, but not exclusively, the present invention relates to the use of polymers including thermoplastic materials to form one or more flexible tube body layers, and a method of treatment to enhance the characteristics of the polymer.
    [002] Traditionally flexible tube is used to transport production fluids, such as oil and/or gas and/or water, from one location to another. Flexible tubing is particularly useful in connecting an underwater location (which can be deep water, ie 1000 meters or more) to a location at sea level. The tube can typically have an inside diameter of up to about 0.6 meters. Flexible tubing is generally formed as an assembly of a flexible tubing body and one or more end-fittings. The tube body is typically formed as a combination of layered materials that form a pressure-containing conduit. The tube structure allows large deflections without causing bending stresses that impair the functionality of the tube for its lifetime. The tube body is generally constructed as a combined structure including metallic and polymer layers.
    [003] Unalloyed flexible pipe has been used for developments in deep water (less than 1,005.84 meters (3,300 ft) and ultra-deep water (more than 3,300 ft). that exploration takes place at greater and greater depth where environmental factors are more extreme. For example, in the aforementioned deep water and ultra-deep water environments, the temperature of the ocean bed increases the risk of production fluids cooling to a temperature that can lead to pipe blockage. Greater depths also increase the pressure associated with the environment the hose must operate in. As a result the need for high levels of performance from the hose body layers is increased.
    [004] Flexible pipe can also be used for shallow water applications (eg less than about 500 meters depth) or even for land (terrestrial) applications.
    [005] In flexible pipes, polymer layers are often used, such as PVDF (polyvinylidene fluoride), which can be formed by extrusion. Most polymers will have a certain maximum allowable stress above which the risk of damage to the material is much greater. In flexible pipes where the polymer layer is adjacent to a shielding layer (such as a polymer barrier layer adjacent to the metallic pressure shielding layer), the polymer layer may be subjected to relatively severe highly localized stresses and not uniforms. This is because the shield layer is generally formed from interlocking wires of certain cross-section, and there are certain spaces between adjacent windings. The polymer layer tends to deform and creep into spaces when under pressure.
    [006] For example, it will be understood that a flexible tube is an assembly of a portion of a tube body and one or more end fittings in each of which a respective end of the tube body is terminated. Figure 1 illustrates how tube body 100 can be formed from a combination of layered materials that form a pressure-containing conduit. It should be noted that layer thicknesses are shown for illustration purposes only.
    [007] As illustrated in Figure 1, the tube body may include an optional innermost casing layer 101. The casing provides an interlocking construction that can be used as the innermost layer to fully or partially prevent collapse of an internal pressure sheath 102 by virtue of tube decompression, external pressure, and shielding pressure from stress and mechanical impact loads. As is known in the technical field, there are applications operations in 'soft hole' (ie without the casing) as well as 'gross hole' (with the casing). The carcass layer may be formed from a helically-wound metallic tape having a cross section formed to allow interlocking of adjacent wound tape portions.
    [008] The internal pressure sheath 102 acts as a fluid retaining layer and comprises the polymer layer that ensures the integrity of the internal fluid. It should be understood that this layer may itself comprise a series of sublayers. It will be appreciated that when the optional carcass layer is used the internal pressure sheath is often referred to by those skilled in the art as the barrier layer. In operation without said casing (so called soft bore operation) the internal pressure sheath may be referred to as a liner.
    [009] Additionally, and not shown in figure 1, a wear layer may also be included between the casing layer and internal pressure sheath. The wear (or sacrificial) layer may be the polymer layer (often extruded but sometimes in tape form) intended to provide a smoother surface or bed for the barrier layer to be extruded over what would be the case over the carcass layer, which may have undulations and spaces between coverings; said smoother wear layer surface may allow the barrier layer to experience higher levels of general stress (strain) as a result of bending and pressure stress concentrations in that what is left of the local stress concentrations is relatively small and insignificant. Without said wear layer the extruded polymer barrier may exhibit an undulating inner surface with protruding cusps of material which naturally flow into spaces in the carcass layer during the extrusion process; said cusps act as stress concentrators when the polymer is stressed.
    [0010] An optional pressure shield layer 103 is a structural layer that increases the resistance of the hose to internal and external pressure and mechanical impact loads. The layer also structurally supports the internal pressure sheath, and typically consists of an interlocking construction of wires with an angle of incidence close to 90°.
    [0011] The flexible tube body also includes an optional first strain shield layer 105 and optional second strain shield layer 106. Each strain shield layer is used to sustain internal stress and strain loads. The voltage shield layer is often formed from a plurality of metallic wires (to provide strength to the layer) that are located on an inner layer and are helically wound along the length of the tube at an angle of incidence. typically between about 10° to 55°. Voltage shield layers are often counter wrapped in pairs.
    [0012] The flexible tube body shown also includes optional tape layers 104 which help to contain underlying layers and to some extent prevent abrasion between adjacent layers.
    [0013] The flexible tube body also typically includes optional insulation layers 107 and an outer sheath 108, which comprises a layer of polymer used to protect the tube from ingress of sea water and other external environments, corrosion, abrasion and mechanical damage.
    [0014] Each flexible tube comprises at least one portion, sometimes referred to as a tube body segment or section 100 along with an end-fitting located on at least one end of the flexible tube. An end fitting provides a mechanical device that forms the transition between the flexible tubing body and a connector. The different layers of tube as shown, for example, in figure 1 are terminated at the end fitting in such a way as to transfer the load between the flexible tube and the connector.
    [0015] Figure 2 illustrates an elevator assembly 200 suitable for transporting production fluid such as oil and/or gas and/or water from a subsea site 201 to a floating platform 202. For example, in Figure 2 the subsea site 201 includes a subsea flow line. The flexible flow line 205 comprises a flexible tube, which is found completely or in part on the ocean floor 204 or buried below the ocean floor and used in a static application. The floating platform can be provided by a platform and/or buoy or, as illustrated in figure 2, a ship. The elevator assembly 200 is provided as a flexible elevator, that is to say a flexible tube 203 that connects the ship to the installation on the ocean bed. Flexible tube can be in flexible tube body segments with end connection fittings.
    [0016] It will be noted that there are different types of elevator, as is well known to those skilled in the art. Modalities of the present invention can be used with any type of elevator, such as a freely suspended elevator (free catenary elevator), an elevator retensioned to some extent (buoys, chains), elevator fully retensioned or enclosed in a tube (tubes I or J).
    [0017] Figure 2 also illustrates how the flexible tube portions can be used as a flow line 205 or bridge tube 206.
    [0018] According to industry regulations, all flexible pipe structures must pass a Factory Acceptance Test (FAT) prior to sale. This involves pressurizing a pipe hole with a fluid such as water to 1.5 times the pressure of usual use. Water is thus a means of pressurizing.
    [0019] The application of internal pressure (i.e., pressure from inside the hole) to the tube produces radial expansion in all layers and this is when the polymer layer undergoes deformation and tends to flow into the spaces of a underlying shielding layer. At high pressures (about 8000 psi / 55 MPa or more), the resulting stress distribution within the polymer layer can be highly localized to the areas around spaces, and the polymer material can deform by cavitation instead. of by plastic flow. This can in turn result in the formation of microcracks or microcracks on the radially inner surface of the polymer layer. During any subsequent loading (such as loading experienced during normal use in transporting production fluids) said microcracks may then extend to form longer/deeper cracks through the polymer layer. This increases the risk of polymer layer failure and can actually lead to loss of pressure containment, having an adverse effect on hose life.
    According to a first aspect of the present invention there is provided a method of producing a flexible tube body, comprising: providing a tubular layer; and directing a chemical reactant toward the surface portion of the tubular layer, wherein the tubular layer comprises an extruded polymer, and wherein the chemical reactant is suitable for changing one or more physical or mechanical properties of a proportion of the thickness of the extruded tubular layer.
    [0021] According to a second aspect of the present invention there is provided a flexible tube body formed by a process comprising: providing the tubular layer; and directing a chemical reagent toward the surface portion of the tubular layer, wherein the tubular layer comprises an extruded polymer, and wherein the chemical reagent is suitable for changing one or more physical or mechanical properties of the thickness ratio of the extruded tubular layer.
    [0022] According to a third aspect of the present invention there is provided a flexible tube body for transporting oil or gas or other said fluid from a subsea location, comprising: a tubular layer comprising a polymer, wherein the layer tubular has a radially inner edge portion or a radially outer edge portion that has an elastic modulus that is lower than the remainder of the tubular layer.
    According to a fourth aspect of the present invention there is provided a method substantially as described herein with reference to the drawings.
    According to a fifth aspect of the present invention there is provided a flexible tube body substantially as described herein with reference to the drawings.
    Certain embodiments of the present invention provide the advantage that a flexible tube body is provided by being treated to reduce, inhibit or prevent microcracks.
    Certain embodiments of the present invention provide the advantage that a method of treating a flexible tube body is provided to reduce, inhibit or prevent microcracks, which can be conveniently incorporated into current tube manufacturing processes.
    [0027] Embodiments of the present invention are further described hereinafter with reference to the accompanying drawings, in which: Figure 1 illustrates a flexible tube body; Figure 2 illustrates an elevator assembly; Figure 3 shows a flow diagram illustrating a method of providing a flexible tube; Figure 4 illustrates a schematic representation of the method of Figure 3; Figure 5 shows another flow diagram illustrating a method of providing a flexible tube; and Figure 6 illustrates a method of providing a flexible tube.
    [0028] In the drawings like reference numbers refer to like parts.
    [0029] Figures 3 and 4 illustrate an embodiment of the present invention in which a flexible tube body 400 is manufactured. In the first step S11 a tubular length of polymeric material is provided to form a polymeric layer 401 of the flexible tube body. In said example, the polymeric material is PVDF and formed as the wear layer 401 of the tube body, and is provided by extrusion over the preformed casing layer (not shown) in a known manner.
    [0030] In the second step S12, before or while the barrier layer 403 is being formed (step S13), a treatment is carried out whereby the polymeric layers are treated with a chemical. Here, acetone is sprayed from a nozzle 407 located at a position close to the point at which the barrier layer 403 is being applied to the surface of the wear layer 401. A spray or mist or liquid that completely encloses circumferentially of acetone 409 is provided over an area of wear layer 401 just before superforming the barrier layer 403, the acetone presenting to and treating adjacent surfaces not only of the polymer barrier but also the wear layers 401, 403.
    [0031] Nozzle 407 can be positioned to direct spray between wear layer 401 and barrier layer 403. Spray 409 substantially coats the hose body portion on both the radially outer surface of the layer of wear and the radially inner surface of the barrier layer. Chemical spray 409 in contact with polymer layers 401 and 403 is capable of reacting with the layers to chemically treat the surface of polymers on said surfaces.
    [0032] In the third step S13, an additional tubular length of polymeric material 403 is provided. In this example, the polymeric material is also PVDF and formed as the barrier layer 403 of the tube body. Barrier layer 403 is provided by extrusion over wear layer 401 in a known manner.
    [0033] In the present embodiment, extrusion is performed by directing PVDF in a flowable state towards the wear layer 401 via a nozzle 405 and formed around the wear layer 401 using an extrusion head and tip (not shown ) to control the shape and concentric characteristic of said tubular additional barrier layer 403 being formed. At the same time, the formed layers of flexible tube (including the casing layer and the wear layer 401) are moved in a horizontal direction indicated by arrow A in the direction of the longitudinal axis of the tube. This allows the flowable material to cover the wear layer and form the additional tubular layer 403.
    [0034]Although the above description refers to the use of acetone, many chemicals can be used in order to change a physical property of the polymeric bed. The chemical can be an oil or hydrocarbon fluid, a polar solvent (such as common alcohols), or non-polar solvents (for example, benzene or toluene), or ionic or supercritical liquid solvents. Additional examples of possible chemicals are: dimethyl sulfoxide, Methyl Ethyl Ketone, Dibutyl Sebacate (DBS), Xylene, Monoethylene Glycol (MEG), and Ethyl Acetate. The chemical may also be a mixture, suspension or alloy of chemicals so as to provide the active ingredient in the desired location, for example, a gel containing the chemical solvent, or an oil and solvent emulsion, or a mixture of a super-low viscosity silicone oil with the active chemical can also be used. Some of these chemicals or combinations of chemicals may require activation using heat or pressure so that they effectively react with the polymer surface.
    [0035] In fact, a carrier fluid may contain pockets or bubbles with the active chemical in said pockets that release their contents either by pressurization between the two polymer layers 401 and 403 or from the extrusion temperature, or as a result of removing the carrier fluid from around said active chemical pockets through evaporation, permeation, or reaction with the surface of the pockets.
    [0036] Additionally the polymer coating or wear layer can be dosed with the active chemical in such a way that the active chemical is released over time. Said release will act on the extruded layer over the top and provide the necessary and desired chemical treatment to the inner surface of the barrier layer.
    [0037]With the formation of the complete hose body, this can be immediately or later followed by FAT.
    [0038] Acetone treatment of polymer layers is used to change one or more surface properties of the layers. In this case, the physical property includes the stiffness or elastic modulus (Young's modulus of elasticity) and yield strength. The chemical acts as a semi-solvent, which has the effect of softening the polymer without dissolving the polymer.
    [0039] It has been observed by the inventors that, surprisingly, by chemically treating the polymer layer, such as the barrier layer of a hose body, micro-cracks in the layer during subsequent pressurization of the hose body are reduced or avoided ( for example, during Factory Acceptance Testing or when the pipe body is in use to transport production fluids or inject fluids into a well to maintain reservoir pressure). That is, as a result of the treatment, the polymer layer must be more resistant to cracking and cracking under pressure from the pipe bore. The treatment is applied in a controlled manner so that it only affects the surface portion of the layer. This change in molecular structure of the radially inner surface of the layer is sufficient to prevent microcracks although the radially outer portion of the layer (which is the portion that is pushed between spaces in an underlying shield layer) is not treated. It is observed that the product-chemical treatment increases the elasticity and strength of the polymer under pressure on the inner surface sufficiently to prevent the initiation of microcracks. The relative softening of the material in the radially inner surface area causes the polymer material to move into any spaces that are present between the windings of an underlying shield layer when under pressure. This helps the polymer to partially flow into the spaces without cavitation and under relatively low tension. Once the polymer has moved the desired amount within the spaces, as a result of the treatment stage, the polymer remains in that position.
    [0040] Therefore, the areas of the polymeric layer, which may have been subjected to localized high stress under high pressure (from the FAT or in use) in known tube arrangements due to the proximity of the spaces, are not subjected to such high voltage in additional use. That is, even when the tube body is under high pressure in FAT or wear, the stress levels are not as high as other known arrangements. This reduction has been shown to significantly or completely prevent any micro-cracks in the polymer layer during its future use after the treatment stage, including during FAT and use in transporting production fluids.
    [0041] The influence on the polymer by the treatment stage can be permanent or temporary. If the influence is permanent, then the polymer layer (eg 403 barrier layer) will have the aforementioned advantages in terms of reduced or zero chance of microcracks in future use as a flexible tube. If the influence is temporary, then the resulting polymer layer will have long enough benefits for the benefits to be seen during FAT.
    [0042] It should be noted that chemical treatment on the surface portion of the polymer layer such as layer 403 can be seen to weaken the surface properties of the polymer layer (permanently or temporarily). However, said surface portion may only be a very small proportion of the total cross-sectional thickness. For example, the cross-sectional portion of the polymer layer may be just 0.1 mm thick, or 0.5 mm thick, or 1 mm thick, for example. The remaining portion of polymer layer that has not been subjected to treatment, for example approximately 6 mm thick, or 8 mm thick, or 10 mm thick, will remain in full strength and sufficient to properly perform the function of the fluid retention layer. It will be appreciated that the precise thicknesses and materials will depend on the specific parameters of use and can be determined by those skilled in the art.
    [0043] Another embodiment of the present invention is shown in Figure 5. This is similar in some ways to the first embodiment and therefore for the sake of brevity not all details will be repeated.
    [0044] In step S21 a tubular length of polymeric material is provided to form the polymeric layer of a flexible tube body. In this example, the polymeric material is again PVDF and formed as a liner for the tube body, and is provided by extrusion into a mandrel (not shown) in a known manner.
    [0045] In step S22 a treatment stage is performed with which the polymeric layer is treated with a chemical. Here, silicone oil-based fluid is sprayed at a location close to the newly formed polymeric layer (although it is understood that said treatment can be carried out at any time after the formation of the layer). Silicone oil has a lower kinematic viscosity than most silicone oils currently used in industry, for example, with a super-low kinematic viscosity of about 50 cSt (50 mm^s-1) or less, or particularly convenient a kinematic viscosity of less than 20 cSt (20 mm^s-1). A silicone oil-based fluid spray or mist is formed in an area around the coating portion after it is formed. The fluid substantially coats the radially outer surface of the layer and treats the layer in accordance with its outer surface.
    [0046] Optionally, an additional tubular length of polymeric material can be extruded before and/or after the tubular polymeric layer of step S21.
    [0047] With said modality the result is a polymer layer for a flexible tube body that has been treated with a chemical reagent on at least one surface thereof.
    [0048] Another embodiment of the present invention will now be described in which a flexible tube body is manufactured. In a first step a tubular length of polymeric material is provided to form the polymeric layer of the flexible tube body. In said example, the polymeric material is PVDF as a coating of the tube body, and it is provided by extrusion on a mandrel in a known manner.
    [0049] In a second step the resistance layer, which in this case is the pressure shielding layer, is provided over the coating. The pressure shield layer is formed from an elongated strip of carbon steel having a generally Z-shaped cross-sectional profile. The strip is formed from a wire-rolling process to have male and female connector portions. corresponding so that as the strip is wound onto the polymeric layer adjacent windings interlock.
    [0050] In a third step, a treatment stage is performed with which the polymeric layer is treated with a chemical. More specifically, the radially inner surface of the polymeric layer is imbibed with a chemical in order to change at least one physical property of the layer.
    [0051] An example of the treatment stage will now be described with reference to Figure 6. A fluid inlet conduit 502 is connected to the first end 506 of the flexible tube body 501 by means of a pump member 508. The tube body is conveniently stored on a 510 spool at the same time it undergoes the treatment stage. Acetone is then pumped through the tube body. The acetone exiting the second end 514 of the tube body can be recirculated back to the first end of the tube body (in the direction of arrow B via a conduit 516). Said acetone rinse is continued for up to 2 hours.
    [0052] Subsequent to the treatment stage, the tube body can then pass the usual Factory Acceptance Test by pressurizing the tube body to a predetermined pressure, immediately or separately. The tube body can be cut to shorter lengths and the separate lengths then subjected to a FAT. The polymeric layer can only expand into the spaces of the resistance layer at the time of FAT. However, chemical treatment for the inner surface is sufficient to reduce stress and therefore microcracks in the layer.
    [0053] The method of Figure 6 effectively provides a treatment stage in which the radially inner surface of the polymeric layer is exposed to acetone for the predetermined length of time. Exposure causes a change in stiffness of the portion of the polymeric layer on the radially inner side, without detrimental degradation of the polymeric layer. The chemical acts as a semi-solvent, which has the effect of softening the polymer without dissolving the polymer.
    [0054]Various modifications to the detailed drawings as described above are possible. For example, the treated polymeric layer(s) can be any layer(s) of the tube body and not limited to wear layer, liner or barrier layer. The shield layer can similarly be any layer of the flexible tube body such as the resistance layer, the pressure shield layer, the strain shield layer, etc. The polymeric layer does not need to be directly adjacent to a shielding layer; there may be intermediate layers such as a sacrificial tape layer. For the flexible tube body with more than one polymeric layer, the method described above can be employed more than once in order to treat each of the polymeric layers in turn or together. The treatment stage can be carried out directly over the barrier layer with the carcass layer present, as the carcass layer is not fluid-tight and will allow spray or mist to flow between them to access the barrier polymeric layer. The treatment chemical can be incorporated into or combined with the polymer granules used in the extrusion process for an extruded layer or an extruded tape to be wound over the tube as a wear layer, thereby providing the layer with the means of release active chemicals over time, or as a result of an event (such as the application of heat or pressure) from that layer on the adjacent polymer layers.
    [0055]The materials used for the treatment stage can be chosen according to the particular materials of the flexible tube body, with the design, and the future pressure of the FAT test.
    [0056] The chemical reagent can be any reagent suitable for changing the physical property of the polymeric layer. The chemical can be a hydrocarbon oil or fluid, a polar solvent (such as common alcohols), or non-polar solvents (for example, benzene), or ionic or supercritical liquid solvents such as acetone, toluene, dibutyl sebacate, methyl ethyl ketone, ethyl acetate, dimethyl sulfoxide, xylene, monoethylene glycol, silicone oil having a viscosity of about 50 cSt or less, or a combination thereof, or a water dilution thereof.
    [0057] The spray or mist can have any suitable droplet size sufficient to completely or substantially coat the surface of the polymer layer, or a liquid rinse encompassing completely circumferentially can be used instead.
    [0058] The polymer layer may comprise a fluoropolymer such as PVDF, a polyamide such as PA-12 or PA-11, another material such as polyphenylene sulfide (PPS), PP, PFA, HDPE, PEEK, PEX, or a combination of these, and may have additional components such as metallic strands or nanoparticles dispersed in it. Tape-type wear layers may comprise a polymer, such as those listed above, or be of composite construction, bonded or unbonded to the surrounding layers and comprising either a cured matrix or an uncured matrix surrounding metallic or non-metallic reinforcements. metallic, or comprise metallic tapes.
    [0059] The physical property can include stiffness, shape, modulus of elasticity, stress and tension ratio, threshold stress for cracks, surface hardness, surface tension, friction for the movement of polymer fiber chains, distribution of the polymer microstructure chain, and density, for example. The radially inner surface, or the radially outer surface, or both surfaces can be chemically treated.
    [0060] With the arrangements described above a flexible tube body is provided which has been treated to reduce, inhibit or prevent microcracks. The method of treating a flexible tube body can be conveniently incorporated into current tube manufacturing processes.
    [0061] As such, the operating parameters of temperature and pressure of the hoses will be extended. That is, the tubes will be able to withstand greater operational repressions compared to known arrangements.
    [0062] The present invention can be of particular use for high pressure applications, such as use at 15000 psi (103 MPa) and above.
    [0063] It should be understood that the present invention is broadly applicable to the coaxial body of pipe structures including two or more layers fabricated from a variety of possible materials, for example, including some or all of the layers as shown in figure 1.
    [0064] The present invention is not necessarily limited to the order of steps shown in the flow diagrams.
    [0065] It will be clear to those skilled in the art that the characteristics described in relation to any of the modalities described above may be applicable interchangeably between the different modalities. The embodiments described above are examples to illustrate the various features of the present invention.
    [0066] Throughout the description and claims in the present specification, the terms "comprises" and "contains" and variations thereof means "including, but not limited to", and they are not intended (and not) to exclude other fractions, addi - you, components, integers or stages. Throughout the description and claims of the present specification, the singular encompasses the plural unless the context indicates otherwise. In particular, where the indefinite article is used, the specification is to be understood as contemplating a plurality as well as a singularity, unless the context indicates otherwise.
    [0067] Traits, integers, characteristics, compounds, chemical fractions or groups described in conjunction with a particular aspect, embodiment or example of the present invention are to be understood to apply to any other aspect, embodiment or example described unless it is incompatible with it. All features described in this specification (including any claims, summary and attached drawings), and/or all steps of any method or process so described, may be combined in any combination, except combinations where at least some of said features and/or steps are mutually exclusive. The present invention is not restricted to the details of any of the above embodiments. The present invention extends to any new, or any new combination, of the features described in the present specification (including any claims, abstract and accompanying drawings), or to any new, or any new combination, of the steps of any method or process so described.
    [0068] The reader's attention is directed to all papers and documents that are filed with or prior to this specification in connection with this application and which are open to the public for inspection with this specification, and the contents of all said papers and documents are hereby incorporated by reference.
    权利要求:
    Claims (9)
    [0001]
    1. A method of producing a flexible tube body (400) for transporting production fluids from a subsea location comprising: providing a tubular layer (401); and directing a chemical reagent towards a surface portion of the tubular layer, CHARACTERIZED in that the tubular layer comprising an extruded polymer comprises a fluoropolymer, a polyamide, a polyphenylene sulfide (PPS), PP, PFA, HDPE, PEEK , PEX or a combination thereof, and wherein the chemical reagent has the effect of softening the polymer without dissolving the polymer and is suitable for changing one or more physical or mechanical properties of a proportion of the thickness of the extruded tubular layer to thereby reduce , inhibit or prevent microcracks.
    [0002]
    2. Method according to claim 1, CHARACTERIZED in that the tubular layer is a second tubular layer applied by extrusion over a first tubular layer, and the directing step, as defined in claim 1, is applied to the first layer tubular before extrusion of the second tubular layer.
    [0003]
    3. Method according to claim 1, CHARACTERIZED in that the tubular layer is a second tubular layer applied by extrusion over a first tubular layer, and the directing step, as defined in claim 1, is applied to the second layer tubular after extrusion of the second tubular layer.
    [0004]
    4. Method according to claim 1, CHARACTERIZED in that the tubular layer is a second tubular layer applied by extrusion onto a first tubular layer, and wherein the first tubular layer comprises a polymer additive with the chemical reagent, and wherein the directing step comprises releasing the chemical reagent from the first tubular layer.
    [0005]
    5. Method according to any one of claims 1 to 4, CHARACTERIZED by the fact that the polymer comprises PVDF, PA-11, PA-12, or a mixture of PVDF, PA-11 or PA-12 with at least one selected from PVDF, HDPE, PA-11, PA-12, PEX, PEEK, PPS, PP and PFA.
    [0006]
    6. Method according to any one of claims 1 to 5, CHARACTERIZED by the fact that the chemical reagent comprises acetone, toluene, dibutyl sebacate, methyl ethyl ketone, ethyl acetate, dimethyl sulfoxide, xylene, monoethylene glycol , silicone oil having a kinematic viscosity of about 50 cSt (50 mm2.s-1) or less, or a combination of these, or a water dilution thereof, or wherein the chemical reagent is carried by another benign fluid.
    [0007]
    7. Method according to any one of claims 1 to 6, CHARACTERIZED by the fact that it additionally comprises changing a physical property of part of the tubular layer, temporarily or permanently, with the chemical reagent.
    [0008]
    8. Method, according to claim 7, CHARACTERIZED by the fact that the physical property includes shape, modulus of elasticity, flow limit, stress and stress ratio, threshold stress for cracks, surface hardness, surface tension, friction for the movement of polymer fiber chains, distribution of polymer microstructure chain and density.
    [0009]
    9. Method according to any one of claims 1 to 8, CHARACTERIZED by the fact that it additionally comprises providing a shielding layer (103) and an outer sheath (108) over the tubular layer.
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    DK2653291T3|2018-09-03|
    CA2813262A1|2013-10-19|
    CN107718482A|2018-02-23|
    US9975144B2|2018-05-22|
    AU2013205311A1|2013-11-07|
    EP2653288A1|2013-10-23|
    EP2653288B1|2017-07-05|
    EP2653291B1|2018-08-15|
    BR102013009501B1|2021-02-02|
    CN103372987B|2018-01-19|
    CN103372986A|2013-10-30|
    EP3034921B1|2018-07-25|
    MY161979A|2017-05-31|
    MY167422A|2018-08-27|
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    法律状态:
    2015-06-30| B03A| Publication of a patent application or of a certificate of addition of invention [chapter 3.1 patent gazette]|
    2016-01-19| B25A| Requested transfer of rights approved|Owner name: GE OIL AND GAS UK LIMITED (GB) |
    2018-03-27| B06F| Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]|
    2019-08-27| B06U| Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]|
    2021-04-06| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|
    2021-06-01| B16A| Patent or certificate of addition of invention granted|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 19/04/2013, OBSERVADAS AS CONDICOES LEGAIS. |
    2021-07-27| B25D| Requested change of name of applicant approved|Owner name: BAKER HUGHES ENERGY TECHNOLOGY UK LIMITED (GB) |
    优先权:
    申请号 | 申请日 | 专利标题
    EP12164837.2A|EP2653291B1|2012-04-19|2012-04-19|Method of producing a flexible pipe body|
    EP12164837.2|2012-04-19|
    EP12189971.0|2012-10-25|
    EP12189971.0A|EP2653288B1|2012-04-19|2012-10-25|Method of producing a flexible pipe body|
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